Glycinium 3-carboxy-4-hydroxybenzenesulfonate

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Glycinium 3-carb­oxy-4-hy­droxy­benzene­sulfonate

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The crystal structures of quinolinium 3-carboxy-4-hydroxybenzenesulfonate trihydrate, C9H8N + C7H5O6S 3H2O, (I), 8-hydroxyquinolinium 3-carboxy-4-hydroxybenzenesulfonate monohydrate, C9H8NO + C7H5O6S H2O, (II), 8-aminoquinolinium 3-carboxy-4-hydroxybenzenesulfonate dihydrate, C9H9N2 + C7H5O6S 2H2O, (III), and 2-carboxyquinolinium 3-carboxy-4-hydroxybenzenesulfonate quinolinium-2-carboxylate, C1...

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Methyl 3-carboxy-5-nitrobenzoate

The structure of the title compound, C(9)H(7)NO(6), is essentially planar [maximum deviation 0.284 (2)Å] except for the methyl H atoms. The crystal structure is stabilized by asymmetric O-H⋯O hydrogen bonds linking the hydrogen carboxyl-ates into pairs around the inversion centres. There is also π-π stacking of the benzene rings [centroid-centroid distance 3.6912 (12) Å].

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Bis[glycinium(0.5+)] perrhenate

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Transition metal-free one-pot synthesis of 2-substituted 3-carboxy-4-quinolone and chromone derivatives.

A novel one-pot synthesis of the 2-substituted 3-carboxy-4-quinolone/chromone derivatives from readily available 3-oxo-3-arylpropanoates and amides/acyl chlorides is reported, without any transition metal aid.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2014

ISSN: 1600-5368

DOI: 10.1107/s1600536814004590